Photoelectric effect, phenomenon in which electrically charged particles are released from or within a material when it absorbs electromagnetic radiation. The effect is often defined as the ejection of electrons from a metal plate when light falls on it. In a broader definition, the radiant energy may be infrared, visible, or ultraviolet light, X-rays, or gamma rays; the material may be a solid, liquid, or gas; and the released particles may be ions (electrically charged atoms or molecules) as well as electrons. The phenomenon was fundamentally significant in the development of modern physics because of the puzzling questions it raised about the nature of light—particle versus wavelike behavior—that were finally resolved by Albert Einstein in 1905. The effect remains important for research in areas from materials science to astrophysics, as well as forming the basis for a variety of useful devices.
Discovery and early work
The photoelectric effect was discovered in 1887 by the German physicist Heinrich Rudolf Hertz. In connection with work on radio waves, Hertz observed that, when ultraviolet light shines on two metal electrodes with a voltage applied across them, the light changes the voltage at which sparking takes place. This relation between light and electricity (hence photoelectric) was clarified in 1902 by another German physicist, Philipp Lenard. He demonstrated that electrically charged particles are liberated from a metal surface when it is illuminated and that these particles are identical to electrons, which had been discovered by the British physicist Joseph John Thomson in 1897.
Further research showed that the photoelectric effect represents an interaction between light and matter that cannot be explained by classical physics, which describes light as an electromagnetic wave. One inexplicable observation was that the maximum kinetic energy of the released electrons did not vary with the intensity of the light, as expected according to the wave theory, but was proportional instead to the frequency of the light. What the light intensity did determine was the number of electrons released from the metal (measured as an electric current). Another puzzling observation was that there was virtually no time lag between the arrival of radiation and the emission of electrons. Consideration of these unexpected behaviors led Albert Einstein to formulate in 1905 a new corpuscular theory of light in which each particle of light, or photon, contains a fixed amount of energy, or quantum, that depends on the light’s frequency. In particular, a photon carries an energy E equal to hf, where f is the frequency of the light and h is the universal constant that the German physicist Max Planck derived in 1900 to explain the wavelength distribution of blackbody radiation—that is, the electromagnetic radiation emitted from a hot body. The relationship may also be written in the equivalent form where c is the speed of light and λ is its wavelength, showing that the energy of a photon is inversely proportional to its wavelength.
good explanation
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